منابع مشابه
Trimethyl Phosphite Mediated Simple Synthesis of Coumarins and Azacoumarins Through the Reaction of Phenols or Hydroxypyridines and Dimethyl Acetylenedicarboxylate (DMAD) or Diethyl Acetylenedicarboxylate (DEAD)
Protonation of the reactive intermediate produced in the reaction between trimethyl phosphite and dimethyl acetylenedicarboxylate or diethyl acetylenedicarboxylate by resorcinol, 5-methylresorcinol, 2,5-dihydroxyacetophenone, 4-chloro-2-methylphenol, 4-chloro-3,5-dimethy-lphenol, 4-hydroxypyridine, 2-hydroxypyridine, 3-hydroxypyridine, or 8-hydroxyquinoline leads to vinylphosphonium salts,...
متن کاملSynthesis of novel highly functionalized 4-thiazolidinone derivatives from 4-phenyl-3-thiosemicarbazones.
We present herein the synthesis in good yields of two series of highly functionalized thiazolidinone derivatives from the reactions of various 4-phenyl-3-thio-semicarbazones with ethyl 2-bromoacetate and diethyl acetylenedicarboxylate, respectively.
متن کاملCrystal structures of the dinitrate-bis-(acetylenedicarboxylate) and acetylenedicarboxylate pseudorotaxane complexes of [24-pyrimidinium crown 6]
The reaction of [24-Pyrim C6][NO3]6 ! 8H2O with the monopotassium salt of acetylenedicarboxylic acid yielded single crystals of [24-Pyrim C6][C4O4]2[NO3]2 ! 7 H2O, (1). The compound crystallized in the triclinic space group P1, with a = 9.731(8) Å, b = 10.953(9) Å, c = 14.270 (14) Å, a = 108.06(7)", b = 94.86(7)", c = 99.01(7)", Z = 1, R = 0.0737, R¢ = 0.1024, and 3709 independent reflections. ...
متن کاملtrimethyl phosphite mediated simple synthesis of coumarins and azacoumarins through the reaction of phenols or hydroxypyridines and dimethyl acetylenedicarboxylate (dmad) or diethyl acetylenedicarboxylate (dead)
protonation of the reactive intermediate produced in the reaction between trimethyl phosphite and dimethyl acetylenedicarboxylate or diethyl acetylenedicarboxylate by resorcinol, 5-methylresorcinol, 2,5-dihydroxyacetophenone, 4-chloro-2-methylphenol, 4-chloro-3,5-dimethy-lphenol, 4-hydroxypyridine, 2-hydroxypyridine, 3-hydroxypyridine, or 8-hydroxyquinoline leads to vinylphosphonium salts, whi...
متن کاملA highly efficient cycloaddition of vinylarenes with electron-deficient alkynes affording 1,2-disubstituted-3,4-dihydronaphthalenes catalysed by N,N-dimethylformamide dimethyl acetal.
1,2-Disubstituted-3,4-dihydronaphthalenes could be conveniently synthesized with high yields by the cycloaddition reactions of easily available vinylarenes with electron-deficient alkynes such as dimethyl, or diethyl acetylenedicarboxylate, methyl phenylpropiolate in the presence of DMF.DMA (N,N-dimethylformamide dimethyl acetal) as organocatalyst.
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ژورنال
عنوان ژورنال: Synlett
سال: 2015
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0034-1380502